The Rhino
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He is a supervillain and a frequent adversary of Spider-Man and occasionally the Hulk. Created by writer Stan Lee and artist John Romita, Sr., he first appeared in The Amazing Spider-Man #41 (October 1966).
As part of a Soviet super soldier program, a super-strong polymer was bonded to the Rhino's skin. A dim-witted criminal, the Rhino mostly robs banks and works for more ambitious villains.